N-[4-Chloro-3-(trifluoromethyl)phenyl]-2,2-dimethylpropanamide
نویسندگان
چکیده
In the title compound, C(12)H(13)ClF(3)NO, the C-C-N-C torsion angle between the benzene ring and the pivaloyl group is -33.9 (5)°. In the crystal, molecules are linked via N-H⋯O hydrogen bonds to form chains running parallel to the c axis. Weak van der Waals inter-actions are also observed.
منابع مشابه
1-[4-Chloro-3-(trifluoromethyl)phenyl]-4-phenyl-1H-1,2,3-triazole
In the title compound, C(15)H(9)ClF(3)N(3), the phenyl and chloro-trifluoro-methyl benzene rings are twisted with respect to the planar triazole group, making dihedral angles of 21.29 (12) and 32.19 (11)°, respectively. In the crystal, the mol-ecules pack in a head-to-tail arrangement along the a axis with closest inter-centroid distances between the triazole rings of 3.7372 (12) Å.
متن کامل3-(2-Chloro-3,3,3-trifluoroprop-1-en-1-yl)-2,2-dimethyl-N-[3-(trifluoromethyl)phenyl]cyclopropanecarboxamide
In the title mol-ecule, C(16)H(14)ClF(6)NO, the cyclo-propane ring forms a dihedral angle of 70.82 (18)° with the benzene ring. The torsion angles about the ethyl-ene and amide bonds are -2.2 (5) (Cl-C-C-C) and 0.8 (5)° (O-C-N-C). A supra-molecular chain propagated by glide symmetry along [001] and mediated by N-H⋯O hydrogen bonds is observed in the crystal packing.
متن کامل3-Chloro-6-{4-[3-(trifluoromethyl)phenyl]piperazin-1-yl}pyridazine
The title compound, C(15)H(14)ClF(3)N(4), was synthesized from 3,6-dichloro-pyridazine and 1-[3-(trifluoro-meth-yl)phen-yl]piper-azine. The piperazine ring is flanked by 3-chloro-pyridazine and 3-trifluoro-methyl-phenyl rings and adopts a chair conformation, whereas the 3-chloro-pyridazine and 3-trifluoro-methyl-phenyl rings are planar, with maximum deviations of 0.0069 (13) and 0.0133 (14) Å, ...
متن کامل2-Chloro-N-{3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazol-5-yl}acetamide
The title compound, C(13)H(6)Cl(3)F(3)N(4)O, was synthesized by the reaction of 5-amino-1-[2,6-dichloro-4-(trifluoro-meth-yl)phen-yl]-1H-pyrazole-3-carbonitrile and 2-chloro-acetyl chloride. The five-membered pyrazole ring makes a dihedral angle of 71.5 (3)° with the benzene ring. The -CF(3) group is disordered by rotation, and the F atoms are split over two sets of sites with occupancies of 0....
متن کاملPhenyl N-[4-chloro-3-(trifluoromethyl)phenyl]carbamate
In the mol-ecule of the title compound, C(14)H(9)ClF(3)NO(2), the aromatic rings are oriented at a dihedral angle of 66.49 (3)°. Intra-molecular C-H⋯F and C-H⋯O inter-actions result in the formation of one planar five- and one non-planar six-membered ring. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains.
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012